Soil can provide plants with nitrogen through organic matter mineralization, deposition during rainfall events, and residual inorganic nitrogen in soil. However, plants often need more nitrogen than soil can provide to produce a crop yield of desired quality. As such, nitrogen fertilizers need to be applied.
When you purchase nitrogen fertilizers, you will notice that the guaranteed analysis for essential nutrients contained is provided on the bags or containers. For nitrogen, usually guaranteed analysis for percent of total nitrogen, urea nitrogen, nitrate nitrogen, ammoniacal nitrogen, water soluble nitrogen, water insoluble nitrogen, or slowly available nitrogen is provided. Depending on the fertilizer product, one or more of these forms may be contained. It is important that you read the guaranteed analysis label to understand the percentage and forms of nitrogen fertilizer because different forms of fertilizers behave differently in the soil and are lost from soils in different ways.
Ammoniacal nitrogen undergoes a series of transformations after being applied to soils. For example, ammoniacal nitrogen can be converted to a nitrate form, gaseous form (ammonia), or organic form. If you apply ammoniacal nitrogen on the soil surface when the soil is dry or high in pH, you will lose a significant portion of nitrogen to the atmosphere in the form of ammonia. Windy conditions also favor such loss. With dry or high pH soil conditions, the nitrate, slow release, or controlled release forms of fertilizers are better choices. If you inject ammoniacal fertilizers deep into the soil, then nitrogen loss to the atmosphere in the form of gaseous ammonia is very little. Under optimum soil temperature and moisture conditions, ammoniacal nitrogen can be converted to nitrate nitrogen quickly.

Nitrate nitrogen, either converted from ammoniacal nitrogen or being applied as a nitrate form of fertilizer, also undergoes a series of transformations in soil. Nitrate is water soluble, therefore, leaching is the major loss pathway – often during heavy irrigation, heavy rainfall, and snowmelt events. If your fertilizer product contains mainly a nitrate form of nitrogen, you should avoid applying the fertilizer before heavy rainfall to avoid leaching loss. If you have soil with poor drainage, applying a nitrate form of fertilizer in water logging condition should be avoided because significant portion of nitrate nitrogen can be converted to other gaseous forms of nitrogen and be lost (e.g. nitrous oxide or molecular nitrogen which makes up most of earth’s atmosphere).

Once applied in soils, urea is converted to ammoniacal nitrogen. If urea is applied on the soil surface, it is best if you apply urea fertilizer before rain or irrigation, so that urea is carried into the soils by water. By doing this, you can avoid nitrogen loss to the atmosphere in the form of ammonia gas. In general, it takes about 0.5 inch of rainfall within 24 to 48 hours after surface application to transport urea to the depth that will minimize volatilization loss.
Slow release or controlled release fertilizers reduce nitrogen loss by delaying nitrogen release into the soil. They gradually feed crops during the growth period. Generally, slow-release nitrogen is most beneficial when fertilizer is applied in cold temperatures, on the soil surface, in soil with high leaching potential, or at hillslope locations with poor drainage/high water ponding risk. Carefully managing application rate is still necessary for these fertilizers because excessive application can cause nitrogen loss. The portion of nitrogen that is converted to ammoniacal and nitrate forms but not taken up by plants can still be lost to the environment.
Knowing that nitrogen is not held by soil and can be lost if not taken up by plants, the timing of nitrogen application is important to minimize nitrogen loss from your soil. It is best that you synchronize nitrogen availability with plant requirements and look at weather forecasts before fertilizer application.
For questions on fertilizers, contact the UConn Soil Nutrient Analysis Laboratory (email soiltest@uconn.edu or call 860-486-4274) or contact your local Cooperative Extension Center. For any other gardening questions, contact the UConn Home & Garden Education Center (email ladybug@uconn.edu or call 877-486-6271).
Haiying Tao, PhD